Non-innocent Redox Behavior of Amidinato Ligands: Spectroscopic Evidence for Amidinyl Complexes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F14%3A00437918" target="_blank" >RIV/61388955:_____/14:00437918 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/zaac.201400306" target="_blank" >http://dx.doi.org/10.1002/zaac.201400306</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/zaac.201400306" target="_blank" >10.1002/zaac.201400306</a>
Alternative languages
Result language
angličtina
Original language name
Non-innocent Redox Behavior of Amidinato Ligands: Spectroscopic Evidence for Amidinyl Complexes
Original language description
The compounds [Ru-II(bmaa(-))(bpy)(2)](PF6) [1(PF6)], [Ru-II(bmaa(-))(Cym)Cl] (2), and [Ru-II(bmaa(-))(Cym)(py)](PF6) [3(PF6)] [bmaa(-) = N,N-bis(4-methoxyphenyl)acetamidinato, bpy = 2,2'-bipyridine, Cym = p-cymene, py = pyridine] were studied spectroelectrochemically (EPR, UV/Vis) to reveal metal-centered oxidation for 1(+) but bmaa(-)-based oxidation to yield amidinyl ligands in 2(+) and 3(2+).
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Zeitschrift für anorganische und allgemeine Chemie
ISSN
0044-2313
e-ISSN
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Volume of the periodical
640
Issue of the periodical within the volume
14
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
2781-2787
UT code for WoS article
000344792300022
EID of the result in the Scopus database
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