Spectroscopic characterization of different structural forms of the new promising energetic material FOX-7 in different solvents

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F15%3A00437239" target="_blank" >RIV/61388955:_____/15:00437239 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.molstruc.2014.11.014" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2014.11.014</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.molstruc.2014.11.014" target="_blank" >10.1016/j.molstruc.2014.11.014</a>

Result language

angličtina

Original language name

Spectroscopic characterization of different structural forms of the new promising energetic material FOX-7 in different solvents

Original language description

UV?vis, IR and NMR spectroscopy were utilized as direct monitoring techniques for structure changes of a new promising energetic material FOX-7 in different protic and aprotic solvents. The dissolved FOX-7 indicates changes in molecular structure as compared with that in solid-state. The push?pull properties of the molecule together with the effects of solvents result in charge separated zwitterion formed in solution. By combination of different spectroscopic techniques, structural changes of charge-separated molecule of FOX-7 were described in dependence on the solvent properties, temperature, proton activity and concentration. From the analytical point of view, the lowest detectable concentration of FOX-7 using UV? vis spectra was determined to approximately 6 x 10-7 mol L-1.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CG - Electrochemistry

OECD FORD branch

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Project

<a href="/en/project/GA13-21704S" target="_blank" >GA13-21704S: Electrochemically active calix[4]arenes and their use for preparation of new receptors and (bio)sensors</a><br>

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2015

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Molecular Structure

ISSN

0022-2860

e-ISSN

—

Volume of the periodical

1083

Issue of the periodical within the volume

MAR 2015

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

7

Pages from-to

10-16

UT code for WoS article

000348879500002

EID of the result in the Scopus database

2-s2.0-84919340434