FOX-7 - Study of Reduction Products of Spectroelectrochemical Methods

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F12%3A00377236" target="_blank" >RIV/61388955:_____/12:00377236 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
FOX-7 - Study of Reduction Products of Spectroelectrochemical Methods
Original language description
A new energetic material 2,2-dinitroethene-1,1-diamine (FOX-7) is recently broadly tested because of its high performance and very low sensitivity. On the other hand, its electrochemical and redox properties have not been studied yet. Our results show that FOX-7 is reduced in aprotic solvents only by two one-electron steps up to -2.9 V. The color changes during reduction of FOX-7 and reversibility of the redox process indicate the presence of radical intermediates. Therefore in situ UV-vis-NIR and ESR spectroelectrochemical investigations were performed. The products after exhaustive electrolyses were separated by HPLC and are identified by mass spectrometry. The possible formation of gaseous products was followed online EC-GC.
Czech name
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Czech description
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Project
<a href="/en/project/GAP206%2F11%2F0727" target="_blank" >GAP206/11/0727: New type of connection between electrochemistry and mass spectrometry - mechanistic studies of redox reactions of organic compounds</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Article name in the collection
XXXII. Moderní elektrochemické metody. Sborník přednášek
ISBN
978-80-905221-0-7
ISSN
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e-ISSN
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Number of pages
4
Pages from-to
130-133
Publisher name
BEST servis
Place of publication
Ústí nad Labem
Event location
Jetřichovice
Event date
May 21, 2012
Type of event by nationality
EUR - Evropská akce
UT code for WoS article
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