go to top Electrochemistry and Spectroscopy of an Energetic Material FOX-7. A molecular Approach to Degradation Mechanism

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F12%3A00386139" target="_blank" >RIV/61388955:_____/12:00386139 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

go to top Electrochemistry and Spectroscopy of an Energetic Material FOX-7. A molecular Approach to Degradation Mechanism

Original language description

Recently synthesized a new energetic material 2,2-dinitroethene-1,1-diamine (FOX-7) has significant potential for application due to its high performance and very low sensitivity. Generally, explosion is based on thermally initiated chain of intramolecular redox reactions. It has been found that electrochemical reduction of FOX-7 in aqueous as well as in non-aqueous solutions is also able to provoke the chain of follow-up processes leading to total decomposition of the parent substance. As intermediatesradical species were proved in aprotic media. Moreover, instead of organic amines, namely gaseous products were identified after exhaustive electrochemical reduction. For these investigations various electrochemical methods both in analytical, as well as in preparative scale were utilized, together with UV-Vis spectroscopy. The detailed understanding of the mechanism and analysis of individual reaction steps is under further study.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CG - Electrochemistry

OECD FORD branch

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Project

<a href="/en/project/ME09002" target="_blank" >ME09002: Chemical and Electrochemical Properties of Aromatic Dialdehydes and their Derivatives, Chemical Principles of Sensors for Aminoacids and New Disinfection Processes</a><br>

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2012

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

International Review of Chemical Engineering

ISSN

2035-1755

e-ISSN

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Volume of the periodical

4

Issue of the periodical within the volume

6

Country of publishing house

BG - BULGARIA

Number of pages

7

Pages from-to

554-560

UT code for WoS article

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EID of the result in the Scopus database

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