Electrochemically initiated degradation of a new energetic material 2,2-didnitroethene-1,1-diamine (FOX-7)
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F11%3A00377708" target="_blank" >RIV/61388955:_____/11:00377708 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1149/1.3646927" target="_blank" >http://dx.doi.org/10.1149/1.3646927</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1149/1.3646927" target="_blank" >10.1149/1.3646927</a>
Alternative languages
Result language
angličtina
Original language name
Electrochemically initiated degradation of a new energetic material 2,2-didnitroethene-1,1-diamine (FOX-7)
Original language description
The recently synthesized energetic material 2,2-dinitroethene-1,1-diamine (FOX-7) is interesting not only as an explosive, but also as a molecule with multiple redox centers, where strong electron donors (amino groups) and acceptors (nitro groups) are close to each other. The present fundamental electrochemical study revealed that in aqueous solutions the reduction pathway during the exhaustive electrolysis does not follow the expected pattern but after the first electron transfer a chain of spontaneousintramolecular (eventually intermolecular) redox processes takes place leading not to reduction products, but to a total degradation of the title compound. Since evolution of gaseous products has been detected during the electrolysis, the electrochemically initiated decomposition of the FOX-7 seems to be analogous to the explosion process slowed down by the very low concentration and cooled by the solution.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP206%2F11%2F0727" target="_blank" >GAP206/11/0727: New type of connection between electrochemistry and mass spectrometry - mechanistic studies of redox reactions of organic compounds</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
ECS Transactions
ISBN
978-1-56677-918-0
ISSN
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e-ISSN
—
Number of pages
5
Pages from-to
11-15
Publisher name
The Electrochemical Society
Place of publication
Pennington
Event location
Montreal
Event date
May 1, 2011
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
000300609100002