Electrochemical investigation of 2,2-dinitroethene-1,1-diamine (FOX-7) in aqueous media

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F11%3A00366305" target="_blank" >RIV/61388955:_____/11:00366305 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1007/s10008-011-1533-2" target="_blank" >http://dx.doi.org/10.1007/s10008-011-1533-2</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s10008-011-1533-2" target="_blank" >10.1007/s10008-011-1533-2</a>

Result language

angličtina

Original language name

Electrochemical investigation of 2,2-dinitroethene-1,1-diamine (FOX-7) in aqueous media

Original language description

Redox properties of 2,2-dinitroethene-1,1-diamine (FOX-7) were electrochemically investigated by DC polarography, cyclic voltammetry and preparative electrolyses, and electroreduction products were analysed. The polarographic reduction of FOX-7 in aqueous buffered solutions exhibited a total sum of limiting currents corresponding to the expected 18 electrons. This result fits well with the chemical reduction of this energetic material resulting in ethan-1,2-diamine. Exhaustive electrolysis, however, didnot yield this product and the passed charge for total degradation of this compound corresponds only to 4?7 F. As the main products, gaseous N2, N2O, NO and NH3 were proved by combination EC?GC?MS and, besides that, nitrite anions and ammonia ions wereidentified by other methods. All these observations suggest that instead of electrochemical reduction, an electrochemically initiated degradation process accompanying the exhaustive electrolysis occurs.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CG - Electrochemistry

OECD FORD branch

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Project

<a href="/en/project/ME09002" target="_blank" >ME09002: Chemical and Electrochemical Properties of Aromatic Dialdehydes and their Derivatives, Chemical Principles of Sensors for Aminoacids and New Disinfection Processes</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2011

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Solid State Electrochemistry

ISSN

1432-8488

e-ISSN

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Volume of the periodical

15

Issue of the periodical within the volume

10

Country of publishing house

DE - GERMANY

Number of pages

7

Pages from-to

2133-2139

UT code for WoS article

000295867100009

EID of the result in the Scopus database

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