Strange Redox Behavior of 1,1-Diamino-2,2-dinitroethene

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F10%3A00357060" target="_blank" >RIV/61388955:_____/10:00357060 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Strange Redox Behavior of 1,1-Diamino-2,2-dinitroethene
Original language description
The expected product of polarographic reduction of 1,1-diamino-2,2-dinitroethene (FOX-7) in aqueous buffered solutions is ethan-1,2-diamine. But exhaustive electrolysis did not show this product. The main products are gases. Due to combination of electrochemistry and GC and with MS analysis were found following gaseous products: N-2, NO, N2O, H2O. However, no carbon containing gaseous product was found. A part of products remains probably in the water solution as inorganic ions. The degradation processaccompanying the exhaustive electrolysis seems to be analogous to the reactions during explosion, but under very low concentration, cooled and slowed down by the solvent.
Czech name
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Czech description
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Project
<a href="/en/project/ME09002" target="_blank" >ME09002: Chemical and Electrochemical Properties of Aromatic Dialdehydes and their Derivatives, Chemical Principles of Sensors for Aminoacids and New Disinfection Processes</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Article name in the collection
Sborník přednášek. XXX: Moderní elektrochemické metody
ISBN
978-80-254-6710-7
ISSN
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e-ISSN
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Number of pages
4
Pages from-to
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Publisher name
BEST servis
Place of publication
Ústí nad Labem
Event location
Jetřichovice
Event date
May 24, 2009
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
000283050900038

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