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Electrochemical and spectrometric study of FOX-7 in aprotic solvents

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F11%3A00361543" target="_blank" >RIV/61388955:_____/11:00361543 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Electrochemical and spectrometric study of FOX-7 in aprotic solvents

  • Original language description

    2,2-Dinitroethene-1,1-diamine (FOX-7) is a recently developed and broadly tested energetic material with high efficiency and low sensitivity. Generally, explosion is based on thermally initiated chain of intramolecular redox reactions. Recently it has been found that electrochemical reduction in aqueous solutions is also able to provoke the chain of follow-up processes leading to total decomposition of the parent substance yielding gaseous products analogously like during explosion. Similarly, results from reductive electrolysis of FOX-7 in aprotic solvents show analogous course of degradation. The first transferred electron activates the molecule and initiated the formation of colored radical intermediates that have been spectroscopically characterized

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CG - Electrochemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/ME09002" target="_blank" >ME09002: Chemical and Electrochemical Properties of Aromatic Dialdehydes and their Derivatives, Chemical Principles of Sensors for Aminoacids and New Disinfection Processes</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2011

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Sborník přednášek. XXXI. Moderní elektrochemické metody

  • ISBN

    978-80-254-9634-3

  • ISSN

  • e-ISSN

  • Number of pages

    4

  • Pages from-to

    149-152

  • Publisher name

    BEST servis

  • Place of publication

    Ústí nad Labem

  • Event location

    Jetřichovice

  • Event date

    May 23, 2011

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article