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Electrochemical and Spectrophotometric Study of the Hydration of Orthophthalaldehyde and Its Reaction with Amines and Amino Acids

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F15%3A00446947" target="_blank" >RIV/61388955:_____/15:00446947 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1149/06626.0013ecst" target="_blank" >http://dx.doi.org/10.1149/06626.0013ecst</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1149/06626.0013ecst" target="_blank" >10.1149/06626.0013ecst</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Electrochemical and Spectrophotometric Study of the Hydration of Orthophthalaldehyde and Its Reaction with Amines and Amino Acids

  • Original language description

    Reactions of orthophthalaldehyde (OPA) with aliphatic ?-amino acids and with aliphatic primary amines were studied in buffered aqueous solution and in non-aqueous acetonitrile. For comparison lysine and glycine ethyl ester were used. The role of the substitution on the ?-carbon was discovered and the effect of OPA hydration on the course of the reaction was also investigated. In contrary to the published information, the dialdehydic unhydrated form is not the primary reactive species and for the successful reaction of OPA with amines, the presence of water is necessary.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CG - Electrochemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ECS Transactions

  • ISSN

    1938-5862

  • e-ISSN

  • Volume of the periodical

    66

  • Issue of the periodical within the volume

    26

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

    13-22

  • UT code for WoS article

  • EID of the result in the Scopus database

    2-s2.0-84940377798