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Heterogeneous Lipid Distributions in Membranes as Revealed by Electronic Energy Transfer

Result description

The techniques achieving the highest resolution only can characterize/nmembrane heterogeneities on the lowest molecular level. When F€orster resonance/nenergy transfer (FRET) is combined with Monte-Carlo (MC) simulations and is/napplied to the measurement of nanodomain/pore sizes it reaches an unbeatable/nresolution of 2–50 nm. While other techniques start being less efficient at such/nshort distances FRET is most efficient in this region. Here, usefulness of/nMC-FRET is demonstrated on three different systems that contain heterogeneously/ndistributed lipids: a nanoscopically phase separated bilayer, a bilayer containing/npores and finally on bicelles consisting of highly curved and flat regions. Moreover,/nthis paper gives the reader information on how a FRET experiment should be/ndesigned to achieve the highest FRET resolution but also which experimental/nconditions should be avoided. The theory describing FRET between randomly/ndistributed donors and acceptors in a lipid bilayer is also described in this paper as/nwell as reasons are explained why for heterogeneous probe distribution MC simulations/nshould rather be used.

Keywords

FRETdomainspores

The result's identifiers

Alternative languages

  • Result language

    angličtina

  • Original language name

    Heterogeneous Lipid Distributions in Membranes as Revealed by Electronic Energy Transfer

  • Original language description

    The techniques achieving the highest resolution only can characterize/nmembrane heterogeneities on the lowest molecular level. When F€orster resonance/nenergy transfer (FRET) is combined with Monte-Carlo (MC) simulations and is/napplied to the measurement of nanodomain/pore sizes it reaches an unbeatable/nresolution of 2–50 nm. While other techniques start being less efficient at such/nshort distances FRET is most efficient in this region. Here, usefulness of/nMC-FRET is demonstrated on three different systems that contain heterogeneously/ndistributed lipids: a nanoscopically phase separated bilayer, a bilayer containing/npores and finally on bicelles consisting of highly curved and flat regions. Moreover,/nthis paper gives the reader information on how a FRET experiment should be/ndesigned to achieve the highest FRET resolution but also which experimental/nconditions should be avoided. The theory describing FRET between randomly/ndistributed donors and acceptors in a lipid bilayer is also described in this paper as/nwell as reasons are explained why for heterogeneous probe distribution MC simulations/nshould rather be used.

  • Czech name

  • Czech description

Classification

  • Type

    C - Chapter in a specialist book

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Book/collection name

    Reviews in Fluorescence 2015

  • ISBN

    978-3-319-24609-3

  • Number of pages of the result

    17

  • Pages from-to

    171-187

  • Number of pages of the book

    367

  • Publisher name

    Springer

  • Place of publication

    New York

  • UT code for WoS chapter