Anodic Oxidation of 18 Halogenated and/or Methylated Derivatives of CB(11)Hu(12)(-)

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F17%3A00474035" target="_blank" >RIV/61388955:_____/17:00474035 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/17:00474233 RIV/61989592:15310/17:73583646
Result on the web
<a href="http://dx.doi.org/10.1021/acs.inorgchem.6b02126" target="_blank" >http://dx.doi.org/10.1021/acs.inorgchem.6b02126</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.inorgchem.6b02126" target="_blank" >10.1021/acs.inorgchem.6b02126</a>

Result language
angličtina
Original language name
Anodic Oxidation of 18 Halogenated and/or Methylated Derivatives of CB(11)Hu(12)(-)
Original language description
Anodic oxidation of [CB11H12](-) and 18 of its halogenated and/or methylated derivatives was examined. Reversible oxidation was found for four of the anions in liquid SO2 and for four more in 1,1,1,3,3,3-hexafluoroisopropyl alcohol. The oxidation occurred at similar to 1 V (for [CB11Me12](-)) up to more than 4 V (for [1-H-(2-6)-F-5-(7-12)-(CF3)(6)-CB11](-)) relative to ferrocene/ferricinium. The anodic peak potentials are reproduced by a set of additive position-sensitive substituent increments.
Czech name
—
Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Project
<a href="/en/project/GAP206%2F11%2F0727" target="_blank" >GAP206/11/0727: New type of connection between electrochemistry and mass spectrometry - mechanistic studies of redox reactions of organic compounds</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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