Redox Properties of Quasi Dimer of 1,3-diphenylisobenzofuran for Singlet Fission
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F17%3A00475136" target="_blank" >RIV/61388955:_____/17:00475136 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Redox Properties of Quasi Dimer of 1,3-diphenylisobenzofuran for Singlet Fission
Original language description
Molecules on the base of 1,3-diphenylisobenzofuran attract an interest because of theirnpossible efficiency for singlet fission This study is focused on electrochemical behaviour ofnthe „quasi dimer“ of 1,3-diphenylisobenzofuran. For characterization of reduction mechanismnin situ UV-vis and EPR spectroscopy were used. The monomer 1,3-diphenylisobenzofurannand its CH2 dimer were added to this study for comparison. The redox properties of bothncompared molecules are similar. The location and the nature of the covalent bridging unit innCH2dimer have small effect onthe redox potentials. But the pi-conjugation in the molecule ofnquasi dimer causes approximately 0.2 V easier oxidization and reduction.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
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OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Result continuities
Project
<a href="/en/project/GA17-18108S" target="_blank" >GA17-18108S: Novel electrochemically active thiacalix[4]arenes and their oxidized analogues as ligands and receptors</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
XXXVII. Moderní elektrochemické metody. Sborník přednášek mezinárodní odborné konference
ISBN
978-80-905221-5-2
ISSN
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e-ISSN
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Number of pages
5
Pages from-to
210-214
Publisher name
Best servis
Place of publication
Ústí nad Labem
Event location
Jetřichovice
Event date
May 15, 2017
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
000432424300047