Charge and spin coupling in copper compounds with hemilabile noninnocent ligands – Ambivalence in three dimensions
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F18%3A00483653" target="_blank" >RIV/61388955:_____/18:00483653 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.ccr.2017.08.006" target="_blank" >http://dx.doi.org/10.1016/j.ccr.2017.08.006</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ccr.2017.08.006" target="_blank" >10.1016/j.ccr.2017.08.006</a>
Alternative languages
Result language
angličtina
Original language name
Charge and spin coupling in copper compounds with hemilabile noninnocent ligands – Ambivalence in three dimensions
Original language description
Both the copper(I) and copper(II) states exhibit coordinative ambiguity as well as a typically increased coordination number after oxidation. This tendency can be used in dynamic redox systems, employing hemilabile innocent ligands. With noninnocent hemilabile ligands such as thioether- or selenoether-substituted o-semiquinone imines there is a complementary reactivity on the ligand side, viz., stepwise electron transfer and coordinative ambivalence. Some resulting combinations have been analyzed for two systems, involving one copper center and one camphorquinone imine or two o-benzoquinone imine components (Qn). Combining redox (CuI/II, Q0/[rad]−/2−) and coordinatively ambivalent metal and ligand components (hemilability) creates variable electronic situations which require experimental and theoretical analysis.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/LTC17052" target="_blank" >LTC17052: Electron-transfer dynamics in complex molecular systems</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Coordination Chemistry Reviews
ISSN
0010-8545
e-ISSN
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Volume of the periodical
355
Issue of the periodical within the volume
JAN 2018
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
7
Pages from-to
173-179
UT code for WoS article
000418977600010
EID of the result in the Scopus database
2-s2.0-85028602451