Electrochemical monitoring of the co-extraction of water with hydrated ions into an organic solvent

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F18%3A00486652" target="_blank" >RIV/61388955:_____/18:00486652 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.elecom.2018.01.017" target="_blank" >http://dx.doi.org/10.1016/j.elecom.2018.01.017</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.elecom.2018.01.017" target="_blank" >10.1016/j.elecom.2018.01.017</a>

Result language

angličtina

Original language name

Electrochemical monitoring of the co-extraction of water with hydrated ions into an organic solvent

Original language description

An electrochemical cell based on the interface between two immiscible electrolyte solutions (ITIES) was designed and used to study the co-extraction of water with hydrated chloride ions from the aqueous to the organic solvent phase. The interfacial potential was controlled by the distribution of a common tetralkylammonium (TAA+) ion. Transfer of hydrated chloride ions is accompanied by the transfer of TAA+, decreasing its concentration on the aqueous side of the interface. Changes in the TAA+ concentration at the interface were monitored by measuring the open circuit potential (OCP). The proposed mechanism of TAACl transport involves a follow-up reaction with the co-extracted water molecules, leading to the formation of clusters of water containing TAACl in the organic phase.

Czech name

—

Czech description

—

Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Project

<a href="/en/project/GA17-09980S" target="_blank" >GA17-09980S: Biomimetic electrochemistry of emulsion micro-droplets at the polarised interface between two immiscible electrolyte solutions</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2018

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Electrochemistry Communications

ISSN

1388-2481

e-ISSN

—

Volume of the periodical

88

Issue of the periodical within the volume

MAR 2018

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

4

Pages from-to

57-60

UT code for WoS article

000426512900013

EID of the result in the Scopus database

2-s2.0-85041483665