Electrochemical Monitoring of the Water Clusters Formation in an Organic Solvent in the Presence of Hydrated Ions
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F18%3A00489892" target="_blank" >RIV/61388955:_____/18:00489892 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Electrochemical Monitoring of the Water Clusters Formation in an Organic Solvent in the Presence of Hydrated Ions
Original language description
An electrochemical method has been developed that makes it possible to monitor thendynamics of the co-extraction of water with hydrated chloride ions at the interface betweenntwo immiscible electrolyte solutions (ITIES). The interfacial potential was controlled by thendistribution of a common tetralkylammonium (TAA+) ion. Changes in the TAA+nconcentration at the interface were monitored by measuring the open circuit potential (OCP).nTransfer of hydrated chloride ions is accompanied by the transfer of TAA+, decreasing itsnconcentration on the aqueous side of the interface. This process involves the co-extraction ofnwater molecules with the hydrated chloride ions and the formation of water clusters in thenorganic solvent phase. The ability to monitor the process from the very beginning of interfacenformation allowed us to obtain important kinetic data.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
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OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Result continuities
Project
<a href="/en/project/GA17-09980S" target="_blank" >GA17-09980S: Biomimetic electrochemistry of emulsion micro-droplets at the polarised interface between two immiscible electrolyte solutions</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
XXXVIII. Moderní elektrochemické metody. Sborník přednášek
ISBN
978-80-905221-6-9
ISSN
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e-ISSN
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Number of pages
4
Pages from-to
151-154
Publisher name
Best Servis
Place of publication
Ústí nad Labem
Event location
Jetřichovice
Event date
May 21, 2018
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
000464596500034