Influence of Adsorption on Electrochemical Reduction of Pyridinium Derivatives
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F18%3A00490086" target="_blank" >RIV/61388955:_____/18:00490086 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Influence of Adsorption on Electrochemical Reduction of Pyridinium Derivatives
Original language description
Two expanded pyridinium-based compounds 1 and 2 were studied by cyclic voltammetry in two different environments. The nonaqueous solution suppresses the adsorption of the compounds on the electrode surface. Adsorption process in aqueous environment was confirmed by typical shape of the curve as well as by the linear dependence of peak current on the scan rate. The shift of standard redox potential in aqueous solution compared to nonaqueous environment toward more negative potential indicates the adsorption of reactant on the electrode surface. Larger shift observed for flat conjugated molecule 1 confirms its stronger adsorption than for the second molecule.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
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OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
XXXVIII. Moderní elektrochemické metody. Sborník přednášek
ISBN
978-80-905221-6-9
ISSN
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e-ISSN
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Number of pages
5
Pages from-to
178-182
Publisher name
Best Servis
Place of publication
Ústí nad Labem
Event location
Jetřichovice
Event date
May 21, 2018
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
000464596500040