Inclusion complex of ?-cyclodextrin and the extended viologen dication: a model of an insulated molecular wire
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F11%3A00361419" target="_blank" >RIV/61388963:_____/11:00361419 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/11:00361419
Result on the web
<a href="http://dx.doi.org/10.1007/s10847-010-9897-y" target="_blank" >http://dx.doi.org/10.1007/s10847-010-9897-y</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10847-010-9897-y" target="_blank" >10.1007/s10847-010-9897-y</a>
Alternative languages
Result language
angličtina
Original language name
Inclusion complex of ?-cyclodextrin and the extended viologen dication: a model of an insulated molecular wire
Original language description
An extended viologen dication 1, containing one viologen subunit, was used as a model for the inclusion complex formation between cyclodextrin (CD) molecules and molecular wires comprising several subunits. UV?Vis and fluorescence spectroscopic measurements confirmed the formation of two types of the inclusion complexes 1:1 and 2:1 between ?CD and 1 in the aqueous solution containing 20% of ethanol. The complex formation constants were obtained from the fluorescence spectral changes: K a = 25 3 mM1 for[?CD?1] complex and K a = 0.21 0.07 mM2 for [(?CD)2?1] complex, respectively. Cyclodextrins ?CD and ?CD do not form the inclusion complexes with 1 in these aqueous solutions. The time-dependent differential capacitance measurements confirmed the adsorption of 1 in the form of a complex at the electrode/electrolyte interface.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Inclusion Phenomena and Macrocyclic Chemistry
ISSN
0923-0750
e-ISSN
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Volume of the periodical
70
Issue of the periodical within the volume
3
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
9
Pages from-to
461-469
UT code for WoS article
000294963800028
EID of the result in the Scopus database
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