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Synthesis of Pt-MWW with controllable nanoparticle size

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F19%3A00517545" target="_blank" >RIV/61388955:_____/19:00517545 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11310/19:10388695

  • Result on the web

    <a href="http://hdl.handle.net/11104/0302880" target="_blank" >http://hdl.handle.net/11104/0302880</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.cattod.2018.07.015" target="_blank" >10.1016/j.cattod.2018.07.015</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis of Pt-MWW with controllable nanoparticle size

  • Original language description

    Zeolites doped with metal nanoparticles have shown the outstanding activity in many processes involving heterogeneous catalysis. The size of metal nanoparticles plays a decisive role in the performance of zeolite catalysts. However, the precise control of the size of nanoparticles is still limited. Herein, we present the synthesis of Pt-MWW zeolites with controllable nanoparticle size using a series of surfactants with different alkyl chain lengths for swelling of layered MCM-22 P. The interlayer distances of swollen materials increases with the length of the surfactant from 1.06 nm (C12OH) to 2.89 nm (C18OH). During swelling, the Pt nanoparticles were intercalated to the interlayer space of MCM-22 P. Further calcination resulted in Pt-MWW materials showing similar morphologies, textural properties and Pt content despite the differences in the initial interlayer distances. The factor that differentiated the synthesized materials was the average diameter of metal nanoparticles. As a result, the average size of Pt nanoparticles increased from 0.85 nm (MCM-22-C12OH-Pt) to 2.04 nm (MCM-22-C18OH-Pt) which is related to the length of the hydrocarbon chain of the surfactant used for the swelling process.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10403 - Physical chemistry

Result continuities

  • Project

    <a href="/en/project/GA17-01440S" target="_blank" >GA17-01440S: Engineering of advanced catalysts from modular parts</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Catalysis Today

  • ISSN

    0920-5861

  • e-ISSN

  • Volume of the periodical

    324

  • Issue of the periodical within the volume

    MAR 2019

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    9

  • Pages from-to

    135-143

  • UT code for WoS article

    000456316500017

  • EID of the result in the Scopus database

    2-s2.0-85050100303