Hydrodehalogenation of organohalides by Et3SiH catalysed by group 4 metal complexes and B(C6F5)3

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F20%3A00522640" target="_blank" >RIV/61388955:_____/20:00522640 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0307103" target="_blank" >http://hdl.handle.net/11104/0307103</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/D0DT00360C" target="_blank" >10.1039/D0DT00360C</a>

Result language
angličtina
Original language name
Hydrodehalogenation of organohalides by Et3SiH catalysed by group 4 metal complexes and B(C6F5)3
Original language description
Catalytic hydrodehalogenation (HDH) of aliphatic organohalides such as trifluorotoluenes by Et3SiH proceeds in the presence of readily available group 4 metal compounds: Cp′2MX2 (Cp′ = η5-C5H5 or η5-C5Me5, X = F, Cl, or Me, M = Ti, Zr, or Hf), CpTiCl3 and TiCl4 with a catalytic amount of B(C6F5)3. The use of metallocenes in combination with the borane activator leads to a better selectivity of the reaction, i.e., suppression of Friedel–Crafts alkylations of arenes.n
Czech name
—
Czech description
—

Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry

Project
<a href="/en/project/GA17-13778S" target="_blank" >GA17-13778S: Aluminum free catalytic system utilizing hydrosilane-B(C6F5)3 adducts as activators in transition metal catalyzed ethylene polymerization</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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