Electrochemical characterization of the artificial metalloenzyme papain-[(η<sup>6</sup>-arene)Ru(1,10-phenanthroline)Cl]<sup>+</sup>
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F20%3A00523422" target="_blank" >RIV/61388955:_____/20:00523422 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0307779" target="_blank" >http://hdl.handle.net/11104/0307779</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jelechem.2020.113882" target="_blank" >10.1016/j.jelechem.2020.113882</a>
Alternative languages
Result language
angličtina
Original language name
Electrochemical characterization of the artificial metalloenzyme papain-[(η<sup>6</sup>-arene)Ru(1,10-phenanthroline)Cl]<sup>+</sup>
Original language description
Electrochemical properties were studied for [(η6-arene)Ru(1,10-phenanthroline)Cl]Cl (arene = C6H5(CH2)2NHCOCH2Cl) organometallic complex 1, protein Papain PAP and its conjugate with organometallic complex 1-PAP. The latter can serve as an artificial metalloenzyme with catalytic activity in transfer hydrogenation. This work demonstrates that AC voltammetry and electrochemical impedance spectroscopy can be used as fast tools to screen the catalytic ability of 1-PAP electrochemically by studies of the catalytic hydrogen evolution reaction (HER). Proteins are known to catalyze this process, but we have shown that additional HER signal associated with the catalytic activity of 1 is observed for its conjugate with Papain 1-PAP.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Electroanalytical Chemistry
ISSN
1572-6657
e-ISSN
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Volume of the periodical
859
Issue of the periodical within the volume
FEB 2020
Country of publishing house
CH - SWITZERLAND
Number of pages
7
Pages from-to
113882
UT code for WoS article
000521509300033
EID of the result in the Scopus database
2-s2.0-85078274394