Crystal engineering with copper and melamine
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F21%3A00544600" target="_blank" >RIV/61388955:_____/21:00544600 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0321440" target="_blank" >http://hdl.handle.net/11104/0321440</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d1ra02903g" target="_blank" >10.1039/d1ra02903g</a>
Alternative languages
Result language
angličtina
Original language name
Crystal engineering with copper and melamine
Original language description
Coordination complexes and polymers are central in inorganic and materials chemistry as a variety of metal centers and coordination geometries lead to a diverse range of interesting properties. Here, size and structure control of gem-like quality monocrystals is demonstrated at room temperature. Using the same set of precursors, the copper-to-melamine molar ratio is adjusted to synthesize either a novel coordination complex of dinuclear copper and melamine (Cu2M1), or a barely-studied coordination polymer of zigzag copper-chlorine chains (Cu4M1). Crystals of the former are dark green and square with a size up to 350 mu m across. The latter is light green, octagonal, and as large as 5 mm across. The magnetic properties of both crystals reflect the low-dimensional arrangements of copper. The magnetic susceptibility of Cu2M1 is modelled with a spin-1/2 dimer, and that of Cu4M1 with a spin-1/2 one-dimensional Ising chain. Controlled synthesis of such quality magnetic crystals is a prerequisite for various magnetic and magneto-optical applications.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
RSC Advances
ISSN
2046-2069
e-ISSN
2046-2069
Volume of the periodical
11
Issue of the periodical within the volume
39
Country of publishing house
GB - UNITED KINGDOM
Number of pages
5
Pages from-to
23943-23947
UT code for WoS article
000678301300009
EID of the result in the Scopus database
2-s2.0-85111092907