Dissociative electron attachment to methyl isocyanide

Result code in IS VaVaI

RIV/61388955:_____/21:00546716 - isvavai.cz

Result on the web

http://hdl.handle.net/11104/0323119

DOI - Digital Object Identifier

10.1140/epjd/s10053-021-00278-2

Result language

angličtina

Original language name

Dissociative electron attachment to methyl isocyanide

Original language description

We experimentally probed the dissociation of methyl isocyanide, CH3NC, via low-energy electron attachment. We have measured the absolute dissociative electron attachment (DEA) cross section for each of the produced ions as a function of incident electron energy. We were able to observe the CH2-, CH3-, CN-, CNC-, CHNC- and CH2NC- anionic fragments as DEA products. Our experimental results are consistent with a previous report, and in addition, we observed the CH2- anion for the first time. To support these experimental results, we also have performed density functional theory (DFT) calculation at the B3LYP/aug-cc-pVTZ level of theory to find out which reaction channel(s) lead to the formation of a given anion.

Czech name

—

Czech description

—

Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10403 - Physical chemistry

Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2021

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

European Physical Journal D

ISSN

1434-6060

e-ISSN

1434-6079

Volume of the periodical

75

Issue of the periodical within the volume

10

Country of publishing house

DE - GERMANY

Number of pages

6

Pages from-to

270

UT code for WoS article

000707006100001

EID of the result in the Scopus database

2-s2.0-85117292745