Dissociative electron attachment to methyl isocyanide
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F21%3A00546716" target="_blank" >RIV/61388955:_____/21:00546716 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0323119" target="_blank" >http://hdl.handle.net/11104/0323119</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1140/epjd/s10053-021-00278-2" target="_blank" >10.1140/epjd/s10053-021-00278-2</a>
Alternative languages
Result language
angličtina
Original language name
Dissociative electron attachment to methyl isocyanide
Original language description
We experimentally probed the dissociation of methyl isocyanide, CH3NC, via low-energy electron attachment. We have measured the absolute dissociative electron attachment (DEA) cross section for each of the produced ions as a function of incident electron energy. We were able to observe the CH2-, CH3-, CN-, CNC-, CHNC- and CH2NC- anionic fragments as DEA products. Our experimental results are consistent with a previous report, and in addition, we observed the CH2- anion for the first time. To support these experimental results, we also have performed density functional theory (DFT) calculation at the B3LYP/aug-cc-pVTZ level of theory to find out which reaction channel(s) lead to the formation of a given anion.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Physical Journal D
ISSN
1434-6060
e-ISSN
1434-6079
Volume of the periodical
75
Issue of the periodical within the volume
10
Country of publishing house
DE - GERMANY
Number of pages
6
Pages from-to
270
UT code for WoS article
000707006100001
EID of the result in the Scopus database
2-s2.0-85117292745