Dissociative attachment of low-energy electrons to acetonitrile
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F21%3A00544965" target="_blank" >RIV/61388955:_____/21:00544965 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0321754" target="_blank" >http://hdl.handle.net/11104/0321754</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1140/epjd/s10053-021-00246-w" target="_blank" >10.1140/epjd/s10053-021-00246-w</a>
Alternative languages
Result language
angličtina
Original language name
Dissociative attachment of low-energy electrons to acetonitrile
Original language description
We experimentally probed the low-energy electron-induced dissociation of acetonitrile and acetonitrile-d3 and performed density functional theory calculations to support the experimental results. The previous studies on electron attachment to acetonitrile presented a number of contradictory findings, which we aimed to resolve in the present study. We observed the formation of H−, CH−2, CH−3, CN−, CCN−, CHCN− and CH2CN− anions and the corresponding deuterated fragments for acetonitrile-d3 by dissociative electron attachment, and measured ion yields curves of each fragment. We saw no evidence for associative electron attachment to form the parent ion in these measurements. We also have measured the kinetic energy and angular distribution of selected fragments using a velocity map imaging (VMI) spectrometer.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/GA20-11460S" target="_blank" >GA20-11460S: Dynamics of electron-induced nuclear motion in cold molecules</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Physical Journal D
ISSN
1434-6060
e-ISSN
1434-6079
Volume of the periodical
75
Issue of the periodical within the volume
AUG 2021
Country of publishing house
DE - GERMANY
Number of pages
13
Pages from-to
230
UT code for WoS article
000688031400001
EID of the result in the Scopus database
2-s2.0-85113816863