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Dissociative attachment of low-energy electrons to acetonitrile

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F21%3A00544965" target="_blank" >RIV/61388955:_____/21:00544965 - isvavai.cz</a>

  • Result on the web

    <a href="http://hdl.handle.net/11104/0321754" target="_blank" >http://hdl.handle.net/11104/0321754</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1140/epjd/s10053-021-00246-w" target="_blank" >10.1140/epjd/s10053-021-00246-w</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Dissociative attachment of low-energy electrons to acetonitrile

  • Original language description

    We experimentally probed the low-energy electron-induced dissociation of acetonitrile and acetonitrile-d3 and performed density functional theory calculations to support the experimental results. The previous studies on electron attachment to acetonitrile presented a number of contradictory findings, which we aimed to resolve in the present study. We observed the formation of H−, CH−2, CH−3, CN−, CCN−, CHCN− and CH2CN− anions and the corresponding deuterated fragments for acetonitrile-d3 by dissociative electron attachment, and measured ion yields curves of each fragment. We saw no evidence for associative electron attachment to form the parent ion in these measurements. We also have measured the kinetic energy and angular distribution of selected fragments using a velocity map imaging (VMI) spectrometer.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10403 - Physical chemistry

Result continuities

  • Project

    <a href="/en/project/GA20-11460S" target="_blank" >GA20-11460S: Dynamics of electron-induced nuclear motion in cold molecules</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    European Physical Journal D

  • ISSN

    1434-6060

  • e-ISSN

    1434-6079

  • Volume of the periodical

    75

  • Issue of the periodical within the volume

    AUG 2021

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    13

  • Pages from-to

    230

  • UT code for WoS article

    000688031400001

  • EID of the result in the Scopus database

    2-s2.0-85113816863