Structural Analysis of Ester Lipids Using Ultraviolet Photodissociation of Their Lithium Adducts
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F24%3A00597838" target="_blank" >RIV/61388955:_____/24:00597838 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/24:00597838
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Structural Analysis of Ester Lipids Using Ultraviolet Photodissociation of Their Lithium Adducts
Original language description
Norrish and Norrish-Yang photochemical reactions were observed in ester groups when lithium adducts of ester lipids were activated by a 213-nm laser. UV photon absorption excited the carbonyl group, leading to γ-hydrogen abstraction from the aliphatic chain. The resulting biradical either fragmented (Norrish type II) or internally recombined to form substituted oxetan-2-ol or cyclobutane (Norrish-Yang), generating secondary fragments. These fragments enabled the differentiation of isomeric triacylglycerol estolides and wax esters.
Czech name
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Czech description
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Classification
Type
O - Miscellaneous
CEP classification
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OECD FORD branch
10406 - Analytical chemistry
Result continuities
Project
<a href="/en/project/LX22NPO5104" target="_blank" >LX22NPO5104: National Institute for Research of Metabolic and Cardiovascular Diseases</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů