Host-guest charge transfer for scalable single crystal epitaxy of a metal-organic framework.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F24%3A00599914" target="_blank" >RIV/61388955:_____/24:00599914 - isvavai.cz</a>
Result on the web
<a href="https://hdl.handle.net/11104/0357326" target="_blank" >https://hdl.handle.net/11104/0357326</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1038/s43246-024-00657-3" target="_blank" >10.1038/s43246-024-00657-3</a>
Alternative languages
Result language
angličtina
Original language name
Host-guest charge transfer for scalable single crystal epitaxy of a metal-organic framework.
Original language description
Methods to grow large crystals provide the foundation for material science and technology. Here we demonstrate single crystal homoepitaxy of a metal-organic framework (MOF) built of zinc, acetate and terephthalate ions, that encapsulate arrays of octahedral zinc dimethyl sulfoxide (DMSO) complex cations within its one-dimensional (1D) channels. The three-dimensional framework is built of two-dimensional Zn-terephthalate square lattices interconnected by anionic acetate pillars through diatomic zinc nodes. The charge of the anionic framework is neutralized by the 1D arrays of Zn ( DMSO ) 6 2 + cations that fill every second 1D channel of the framework. It is demonstrated that the repeatable and scalable epitaxy allows square cuboids of this charge-transfer MOF to grow stepwise to sizes in the centimeter range. The continuous growth with no size limits can be attributed to the ionic nature of the anionic framework with cationic 1D molecular fillers. These findings pave the way for epitaxial growth of bulk crystals of MOFs.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Communications Materials
ISSN
2662-4443
e-ISSN
2662-4443
Volume of the periodical
5
Issue of the periodical within the volume
1
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
220
UT code for WoS article
001337131000005
EID of the result in the Scopus database
2-s2.0-85206255058