Dehydrogenation of methanol by vanadium-oxide and -hydroxide cluster cations in the gas phase
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F07%3A00089543" target="_blank" >RIV/61388963:_____/07:00089543 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Dehydrogenation of methanol by vanadium-oxide and -hydroxide cluster cations in the gas phase
Original language description
A reactivity screening of vanadium-oxide and -hydroxide cluster cations, VmOn+ and VmOn-1(OH)+ (m = 1 - 4, n = 1 - 10) with methanol reveals that only high-valent vanadium-oxide clusters are reactive with respect to oxidation, whereas low-valent clusterdehydrogenate methanol via elimination of H2.
Czech name
Dehydrogenace methanolu pomocí kationtů klastrů oxidu a hydroxidu vanadia v plynné fázi
Czech description
Zkoumání reaktivity kationtů oxidu vanadu a hydroxidových klastrů, VmOn+ a VmOn-1(OH)+ (m = 1 - 4, n = 1 - 10) s methanolem ukazuje, že pouze vyšší oxidační stavy oxidů vanadiových klastrů oxidují methanol, zatímco nižší oxidační stavy klastrů dehydrogenují methanol za eliminace H2.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2007
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Physical Chemistry A
ISSN
1089-5639
e-ISSN
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Volume of the periodical
111
Issue of the periodical within the volume
17
Country of publishing house
US - UNITED STATES
Number of pages
9
Pages from-to
3278-3286
UT code for WoS article
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EID of the result in the Scopus database
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