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On the origin of diastereoselectivity in [2+2+2] cycloisomerization of chiral triynes: Controlling helicity of helicene-like compounds by thermodynamic factors

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F08%3A00306213" target="_blank" >RIV/61388963:_____/08:00306213 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11310/08:12871

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    On the origin of diastereoselectivity in [2+2+2] cycloisomerization of chiral triynes: Controlling helicity of helicene-like compounds by thermodynamic factors

  • Original language description

    Diastereoselective Co(I)-mediated [2+2+2] cycloisomerization of methoxy substituted optically pure aromatic triynes to obtain nonracemic functionalized helicene-like compounds (comprising a penta-, hexa-, and heptacyclic helical scaffold) was studied.

  • Czech name

    O původu diastereoselektivity při [2+2+2] cykloisomerizaci chirálních triynů: Kontrola helicity u helicenů podobných látek pomocí termodynamických faktorů

  • Czech description

    Byla studována diastereoselektivní Co(I)-katalyzovaná [2+2+2] cykloisomerizace methoxysubstituovaných opticky čistých aromatických triynů, která poskytuje neracemické functionalizované helicenům podobné látky (obsahující penta-, hexa- a heptacyclické helikální uspořádání).

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2008

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Organic Chemistry

  • ISSN

    0022-3263

  • e-ISSN

  • Volume of the periodical

    73

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

    2074-2082

  • UT code for WoS article

  • EID of the result in the Scopus database