Beta,beta-Disilylated Sulfones as Versatile Building Blocks in Organic Chemistry ? A New Sulfonyl Carbanion Transmetalation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F10%3A00348884" target="_blank" >RIV/61388963:_____/10:00348884 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Beta,beta-Disilylated Sulfones as Versatile Building Blocks in Organic Chemistry ? A New Sulfonyl Carbanion Transmetalation
Original language description
1,3-Bis(trimethylsilyl)propyl phenyl sulfone undergoes, in contrast to all reported sulfones bearing a-hydrogen atoms, an initial ortho metalation to an aryllithium at low temperature, which transmetalates quantitatively to the corresponding a-sulfonyl organolithium intermediate. Both organolithiums react selectively with aldehydes to give the corresponding products in good to excellent yields with high selectivity.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Synlett
ISSN
0936-5214
e-ISSN
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Volume of the periodical
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Issue of the periodical within the volume
17
Country of publishing house
DE - GERMANY
Number of pages
4
Pages from-to
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UT code for WoS article
000283049600010
EID of the result in the Scopus database
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