1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F11%3A00360880" target="_blank" >RIV/61388963:_____/11:00360880 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.jfluchem.2011.03.011" target="_blank" >http://dx.doi.org/10.1016/j.jfluchem.2011.03.011</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jfluchem.2011.03.011" target="_blank" >10.1016/j.jfluchem.2011.03.011</a>

Result language

angličtina

Original language name

1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds

Original language description

Tetraethyl fluoromethylenebisphosphonate in the presence of cesium carbonate in DMF undergoes efficient 1,4-addition to Michael acceptors having terminal double bond such as alpha,beta-unsaturated ketones, esters, sulfones, sulfoxides, and phosphonates to yield the corresponding adducts (alpha-alkyl-alfa-fluoromethylenebisphosphonates) in good to excellent yields.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

<a href="/en/project/GP203%2F08%2FP310" target="_blank" >GP203/08/P310: Nucleophilic introduction of fluorinated groups using organo-phosphorus compounds</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2011

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Fluorine Chemistry

ISSN

0022-1139

e-ISSN

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Volume of the periodical

132

Issue of the periodical within the volume

5

Country of publishing house

CH - SWITZERLAND

Number of pages

4

Pages from-to

363-366

UT code for WoS article

000291286000009

EID of the result in the Scopus database

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