A Modular Approach to Aryl-C-ribonucleosides via the Allylic Substitution and Ring-Closing Metathesis Sequence. A Stereocontrolled Synthesis of All Four alpha-/beta- and D-/L-C-Nucleoside Stereoisomers

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F11%3A00368189" target="_blank" >RIV/61388963:_____/11:00368189 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/jo201110z" target="_blank" >http://dx.doi.org/10.1021/jo201110z</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jo201110z" target="_blank" >10.1021/jo201110z</a>

Result language
angličtina
Original language name
A Modular Approach to Aryl-C-ribonucleosides via the Allylic Substitution and Ring-Closing Metathesis Sequence. A Stereocontrolled Synthesis of All Four alpha-/beta- and D-/L-C-Nucleoside Stereoisomers
Original language description
Iridium(I)-catalyzed allylation of the enantiopure monoprotected copper(I) alkoxides with enantiopure allylic carbonates has been developed as the key step in a new approach to C-nucleoside analogues. The synthesis continued by ring-closing metathesis and dihydroxylation. This approach allows the synthesis of all four combinations of alpha/beta and D/L-diastereoisomers.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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