Development of (2-bromo-1,1,2,2-tetrafluoroethyl)(phenyl)sulfane as tetrafluoroethyl-radical and tetrafluoroethylene-diradical synthons for additions to alkenes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F13%3A00421786" target="_blank" >RIV/61388963:_____/13:00421786 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jfluchem.2013.07.012" target="_blank" >http://dx.doi.org/10.1016/j.jfluchem.2013.07.012</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jfluchem.2013.07.012" target="_blank" >10.1016/j.jfluchem.2013.07.012</a>

Result language
angličtina
Original language name
Development of (2-bromo-1,1,2,2-tetrafluoroethyl)(phenyl)sulfane as tetrafluoroethyl-radical and tetrafluoroethylene-diradical synthons for additions to alkenes
Original language description
PhSCF2CF2Br in the presence of tributyltin hydride and substochiometric triethylborane in dichloromethane underwent radical addition to alkenes to give the bromine-free products. Reductive substitution of the phenylsulfanyl group for hydrogen in these adducts provided compounds with the tetrafluoroethyl group. Under the same conditions and in the presence of alkenes, radical addition took place to furnish tetrafluoroethylene-containing alkanes.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GAP207%2F11%2F0421" target="_blank" >GAP207/11/0421: Nucleophilic and radical tetrafluoroethyl and tetrafluoroethylene group transfer.</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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