Reductive activation of sulfur hexafluoride with TEMPOLi: Addition of the pentafluorosulfanyl group and TEMPO to terminal alkenes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F18%3A00493028" target="_blank" >RIV/61388963:_____/18:00493028 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.jfluchem.2018.07.003" target="_blank" >http://dx.doi.org/10.1016/j.jfluchem.2018.07.003</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jfluchem.2018.07.003" target="_blank" >10.1016/j.jfluchem.2018.07.003</a>

Result language
angličtina
Original language name
Reductive activation of sulfur hexafluoride with TEMPOLi: Addition of the pentafluorosulfanyl group and TEMPO to terminal alkenes
Original language description
Modes of activation of sulfur hexafluoride for the synthesis of sulfur pentafluorides are considered. We report an S-F activation of sulfur hexafluoride with TEMPO lithium and subsequent reaction with an alkene affording an aliphatic SF5-containing product, which is isolated in low yield and fully characterized. A mechanism involving a single-electron reduction of sulfur hexafluoride, fragmentation to SF5 radical and its addition to alkene is proposed.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry

Project
<a href="/en/project/GC18-00215J" target="_blank" >GC18-00215J: Novel synthetic approaches to organic sulfur pentafluorides</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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