Infrared Laser-Powered Homogeneous Decomposition of (Chloromethyl)trimethylsilane: 1,2-Cl Shift and Methene Expulsion Yielding Chlorotrimethylsilane.

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F02%3A27013081" target="_blank" >RIV/67985858:_____/02:27013081 - isvavai.cz</a>
Alternative codes found
RIV/67985858:_____/02:27020046
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Infrared Laser-Powered Homogeneous Decomposition of (Chloromethyl)trimethylsilane: 1,2-Cl Shift and Methene Expulsion Yielding Chlorotrimethylsilane.
Original language description
The infrared laser-induced sulfur hexafluoride-photosensitized decomposition of (chloromethyl)trimethylsilane affords chlorotrimethylsilane and ethene as major primary products, showing this reaction occurring via 1,2-Cl shift and methene expulsion. At conditions of higher effective temperature, decomposition of chlorotrimethylsilane and reactions between sulfur hexafluoride and Si-containing compounds become important.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CH - Nuclear and quantum chemistry, photo chemistry
OECD FORD branch
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Project
<a href="/en/project/GA104%2F00%2F1294" target="_blank" >GA104/00/1294: Laser photochemistry of (chloromethyl)silane and silacyclo-pent-3-ene for chemical vapour deposition of Si/C/H and Si/H phases</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2002
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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