Spectroelectrochemical Study of Electron Transfer in the Extended 1,1 '-Bipyridinium Cation

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F15%3A00444404" target="_blank" >RIV/61388963:_____/15:00444404 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/15:00444404
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Spectroelectrochemical Study of Electron Transfer in the Extended 1,1 '-Bipyridinium Cation
Original language description
Electron transfer (ET) in the extended 1, 1 ' -bipyridinium has been investigated by UV Nis/NIR and EPR in-situ spectroelectrochemical techniques. During the in-situ cyclic voltammetric scan no EPR signal was observed at the potential corresponding to the first electron transfer at room temperature, whereas the EPR signal for the subsequent ET steadily increased and was observed even at the potentials corresponding to the fourth electron transfer. The EPR signal was detected for the first electron transfer step only at elevated temperature. The evidence for the presence of comproportionation processes and for the formation of n-dimer is discussed.
Czech name
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Czech description
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Article name in the collection
XXXV. Moderní elektrochemické metody. Sborník přednášek mezinárodní odborné konference
ISBN
978-80-905221-3-8
ISSN
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e-ISSN
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Number of pages
4
Pages from-to
72-75
Publisher name
Srsenová Lenka - Best Servis
Place of publication
Ústí nad Labem
Event location
Jetřichovice
Event date
May 18, 2015
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
000358792900017

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