Direct detection of the mercury-nitrogen bond in the thymine-Hg-II-thymine base-pair with Hg-199 NMR spectroscopy

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F15%3A00444868" target="_blank" >RIV/61388963:_____/15:00444868 - isvavai.cz</a>
Alternative codes found
RIV/68378271:_____/15:00494037
Result on the web
<a href="http://pubs.rsc.org/en/content/articlepdf/2015/cc/c5cc02423d" target="_blank" >http://pubs.rsc.org/en/content/articlepdf/2015/cc/c5cc02423d</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c5cc02423d" target="_blank" >10.1039/c5cc02423d</a>

Result language
angličtina
Original language name
Direct detection of the mercury-nitrogen bond in the thymine-Hg-II-thymine base-pair with Hg-199 NMR spectroscopy
Original language description
We have observed the 1-bond Hg-199-N-15 J-coupling ((1)J(Hg-199,N-15) = 1050 Hz) within the Hg-II-mediated thymine-thymine base pair (T-Hg-II-T). This strikingly large (1)J(Hg-199,N-15) is the first one for canonical sp(2)-nitrogen atoms, which can be asensitive structure-probe of N-mercurated compounds and a direct evidence for N-mercuration.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
—

Project
<a href="/en/project/GAP205%2F10%2F0228" target="_blank" >GAP205/10/0228: Structure and Dynaics of Bioinorganic Complexes</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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