Direct detection of the mercury-nitrogen bond in the thymine-Hg-II-thymine base-pair with Hg-199 NMR spectroscopy
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F15%3A00494037" target="_blank" >RIV/68378271:_____/15:00494037 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/15:00444868
Result on the web
<a href="http://dx.doi.org/10.1039/c5cc02423d" target="_blank" >http://dx.doi.org/10.1039/c5cc02423d</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c5cc02423d" target="_blank" >10.1039/c5cc02423d</a>
Alternative languages
Result language
angličtina
Original language name
Direct detection of the mercury-nitrogen bond in the thymine-Hg-II-thymine base-pair with Hg-199 NMR spectroscopy
Original language description
We have observed the 1-bond 199Hg–15N J-coupling (1J(199Hg,15N) = 1050 Hz) within the HgII-mediated thymine–thymine base pair (T–HgII–T). This strikingly large 1J(199Hg,15N) is the first one for canonical sp2-nitrogen atoms, which can be a sensitive structure-probe of N-mercurated compounds and a direct evidence for N-mercuration.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10610 - Biophysics
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemical Communications
ISSN
1359-7345
e-ISSN
—
Volume of the periodical
51
Issue of the periodical within the volume
40
Country of publishing house
GB - UNITED KINGDOM
Number of pages
4
Pages from-to
8488-8491
UT code for WoS article
000354043200023
EID of the result in the Scopus database
2-s2.0-84928969195