Transition metal complexes bearing NHC ligands substituted with secondary polyfluoroalkyl groups

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F15%3A00453320" target="_blank" >RIV/61388963:_____/15:00453320 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22310/15:43900658
Result on the web
<a href="http://dx.doi.org/10.1039/c5dt02258d" target="_blank" >http://dx.doi.org/10.1039/c5dt02258d</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c5dt02258d" target="_blank" >10.1039/c5dt02258d</a>

Result language
angličtina
Original language name
Transition metal complexes bearing NHC ligands substituted with secondary polyfluoroalkyl groups
Original language description
Using three different approaches, racemic 1-(perfluoroalkyl)ethylamines were synthesized from perfluoroalkyl iodides or perfluoroalkanoic acids, and further transformed to the corresponding N,N'-disubstituted ethane-1,2-diimines and ethane-1,2-diamines as mixtures of diastereoisomers. Their cyclization afforded imidazolium or dihydroimidazolium salts, which led to silver or palladium complexes bearing NHC ligands substituted with secondary polyfluoroalkyl groups. The palladium complexes bearing a throwaway 3-chloropyridine ligand proved to be moderately active in the model Suzuki-Miyaura coupling.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GAP207%2F10%2F1533" target="_blank" >GAP207/10/1533: Fluorous carbenes, complexes and ionic liquids based on perfluoropolyether-substituted imidazolium salts and their applications</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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