Mass Spectrometric Studies of Reductive Elimination from Pd(IV) Complexes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F14%3A10209528" target="_blank" >RIV/00216208:11310/14:10209528 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/14:00427626
Result on the web
<a href="http://dx.doi.org/10.1021/ol403190g" target="_blank" >http://dx.doi.org/10.1021/ol403190g</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ol403190g" target="_blank" >10.1021/ol403190g</a>

Result language
angličtina
Original language name
Mass Spectrometric Studies of Reductive Elimination from Pd(IV) Complexes
Original language description
Reductive elimination of ethane from the palladium(IV) complex [PdMe3(bpy)I] (bpy = 2,2'-bipyridine) is studied by electrospray ionization mass spectrometry. Palladium(IV) complexes can be detected as binuclear clusters [Pd2Me6I(bpy)(2)](+) or as complexes [PdMe3(bpy)(L)](+) stabilized by an electron-donating ligand L. Fragmentation of all palladium(W) complexes is dominated by elimination of ethane which corresponds to the reductive elimination coupling of the methyl groups. The associated energy demands for different complexes reveal that the mononuclear complexes with poorly electron-donating ligands provide the fastest reaction.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GAP207%2F11%2F0338" target="_blank" >GAP207/11/0338: Reaction mechanisms in organometallic chemistry</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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