Competition between Halogen, Hydrogen and Dihydrogen Bonding in Brominated Carboranes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F16%3A00469318" target="_blank" >RIV/61388963:_____/16:00469318 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/16:00469318 RIV/61989592:15310/16:33161272 RIV/00216275:25310/16:39901668
Result on the web
<a href="http://dx.doi.org/10.1002/cphc.201600848" target="_blank" >http://dx.doi.org/10.1002/cphc.201600848</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/cphc.201600848" target="_blank" >10.1002/cphc.201600848</a>
Alternative languages
Result language
angličtina
Original language name
Competition between Halogen, Hydrogen and Dihydrogen Bonding in Brominated Carboranes
Original language description
Halogen bonds are a subset of noncovalent interactions with rapidly expanding applications in materials and medicinal chemistry. While halogen bonding is well known in organic compounds, it is new in the field of boron cluster chemistry. We have synthesized and crystallized carboranes containing Br atoms in two different positions, namely, bound to C-and B-vertices. The Br atoms bound to the C-vertices have been found to form halogen bonds in the crystal structures. In contrast, Br atoms bound to B-vertices formed hydrogen bonds. Quantum chemical calculations have revealed that halogen bonding in carboranes can be much stronger than in organic architectures. These findings open new possibilities for applications of carboranes, both in materials and medicinal chemistry.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ChemPhysChem
ISSN
1439-4235
e-ISSN
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Volume of the periodical
17
Issue of the periodical within the volume
21
Country of publishing house
DE - GERMANY
Number of pages
4
Pages from-to
3373-3376
UT code for WoS article
000388629200006
EID of the result in the Scopus database
2-s2.0-84994351590