The Dominant Role of Chalcogen Bonding in the Crystal Packing of 2D/3D Aromatics
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F14%3A33152152" target="_blank" >RIV/61989592:15310/14:33152152 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/14:00434589 RIV/61388963:_____/14:00434589 RIV/00216275:25310/14:39898432
Result on the web
<a href="http://onlinelibrary.wiley.com/doi/10.1002/anie.201405901/epdf" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/anie.201405901/epdf</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.201405901" target="_blank" >10.1002/anie.201405901</a>
Alternative languages
Result language
angličtina
Original language name
The Dominant Role of Chalcogen Bonding in the Crystal Packing of 2D/3D Aromatics
Original language description
The chalcogen bond is a nonclassical sigma-hole-based noncovalent interaction with emerging applications in medicinal chemistry and material science. It is found in organic compounds, including 2D aromatics, but has so far never been observed in 3D aromatic inorganic boron hydrides. Thiaboranes, harboring a sulfur heteroatom in the icosahedral cage, are candidates for the formation of chalcogen bonds. The phenylsubstituted thiaborane, synthesized and crystalized in this study, forms sulfur center dot center dot center dot pi type chalcogen bonds. Quantum chemical analysis revealed that these interactions are considerably stronger than both in their organic counterparts and in the known halogen bond. The reason is the existence of a highly positive sigma-hole on the positively charged sulfur atom. This discovery expands the possibilities of applying substituted boron clusters in crystal engineering and drug design.
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
—
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Angewandte Chemie - International Edition
ISSN
1433-7851
e-ISSN
—
Volume of the periodical
53
Issue of the periodical within the volume
38
Country of publishing house
DE - GERMANY
Number of pages
4
Pages from-to
10139-10142
UT code for WoS article
000342761700025
EID of the result in the Scopus database
—