Chalcogens act as inner and outer heteroatoms in borane cages with possible consequences for sigma-hole interactions
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F16%3A00471052" target="_blank" >RIV/61388980:_____/16:00471052 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/16:00471052
Result on the web
<a href="http://pubs.rsc.org/en/content/articlehtml/2016/ce/c6ce01861k" target="_blank" >http://pubs.rsc.org/en/content/articlehtml/2016/ce/c6ce01861k</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c6ce01861k" target="_blank" >10.1039/c6ce01861k</a>
Alternative languages
Result language
angličtina
Original language name
Chalcogens act as inner and outer heteroatoms in borane cages with possible consequences for sigma-hole interactions
Original language description
Chalcogen bonds are a subset of sigma-hole interactions and the number of their applications has been increasing rapidly. While chalcogen bonding in organic compounds has been intensively studied in the past decade, it is entirely new in boron cluster chemistry. In this paper, we review the remarkable ability of chalcogenated boron clusters to form strong chalcogen bonds. Chalcogen atoms have a unique property to be incorporated in a boron cluster both innerly and outerly. Various molecular shapes (e.g. icosahedral, bicapped-square antiprismatical) have been computationally analyzed and discussed. No general physical trend has been observed and, therefore, it is recommended to tackle each cluster individually.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
CrystEngComm
ISSN
1466-8033
e-ISSN
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Volume of the periodical
18
Issue of the periodical within the volume
47
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
8982-8987
UT code for WoS article
000392449800001
EID of the result in the Scopus database
2-s2.0-84999801111