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Asymmetric Choreography in Pairs of Orthogonal Rotors

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F18%3A00490119" target="_blank" >RIV/61388963:_____/18:00490119 - isvavai.cz</a>

  • Result on the web

    <a href="https://pubs.acs.org/doi/10.1021/acsomega.7b01580" target="_blank" >https://pubs.acs.org/doi/10.1021/acsomega.7b01580</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/acsomega.7b01580" target="_blank" >10.1021/acsomega.7b01580</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Asymmetric Choreography in Pairs of Orthogonal Rotors

  • Original language description

    An asymmetric mechanism for correlated motion occurring in noninteracting pairs of adjacent orthogonal 1,4-bis(carboxyethynyl) bicyclo[1.1.1] pentane (BCP) rotators 1 in the solid state is unraveled and shown to play an important role in understanding the dynamics in the crystalline rotor, Bu4N+[1(-)]center dot H2O. Single crystal X-ray diffraction and calculation of rotor-rotor interaction energies combined with variable-temperature, variable-field H-1 spin-lattice relaxation experiments led to the identification and microscopic rationalization of two distinct relaxation processes.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10401 - Organic chemistry

Result continuities

  • Project

    <a href="/en/project/7AMB16FR038" target="_blank" >7AMB16FR038: Functional materials based on bicyclo[1.1.1]pentan rotors: organization and dynamics</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ACS Omega

  • ISSN

    2470-1343

  • e-ISSN

  • Volume of the periodical

    3

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    5

  • Pages from-to

    1293-1297

  • UT code for WoS article

    000427933200137

  • EID of the result in the Scopus database

    2-s2.0-85048418318