Asymmetric Choreography in Pairs of Orthogonal Rotors
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F18%3A00490119" target="_blank" >RIV/61388963:_____/18:00490119 - isvavai.cz</a>
Result on the web
<a href="https://pubs.acs.org/doi/10.1021/acsomega.7b01580" target="_blank" >https://pubs.acs.org/doi/10.1021/acsomega.7b01580</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acsomega.7b01580" target="_blank" >10.1021/acsomega.7b01580</a>
Alternative languages
Result language
angličtina
Original language name
Asymmetric Choreography in Pairs of Orthogonal Rotors
Original language description
An asymmetric mechanism for correlated motion occurring in noninteracting pairs of adjacent orthogonal 1,4-bis(carboxyethynyl) bicyclo[1.1.1] pentane (BCP) rotators 1 in the solid state is unraveled and shown to play an important role in understanding the dynamics in the crystalline rotor, Bu4N+[1(-)]center dot H2O. Single crystal X-ray diffraction and calculation of rotor-rotor interaction energies combined with variable-temperature, variable-field H-1 spin-lattice relaxation experiments led to the identification and microscopic rationalization of two distinct relaxation processes.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
<a href="/en/project/7AMB16FR038" target="_blank" >7AMB16FR038: Functional materials based on bicyclo[1.1.1]pentan rotors: organization and dynamics</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ACS Omega
ISSN
2470-1343
e-ISSN
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Volume of the periodical
3
Issue of the periodical within the volume
1
Country of publishing house
US - UNITED STATES
Number of pages
5
Pages from-to
1293-1297
UT code for WoS article
000427933200137
EID of the result in the Scopus database
2-s2.0-85048418318