Enantioselective Complexation of 1‐Phenylethanol with Chiral Compounds Bearing Urea Moiety.

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F18%3A00490484" target="_blank" >RIV/61388963:_____/18:00490484 - isvavai.cz</a>
Alternative codes found
RIV/67985858:_____/18:00490484 RIV/60461373:22310/18:43917053
Result on the web
<a href="http://dx.doi.org/10.1002/chir.22855" target="_blank" >http://dx.doi.org/10.1002/chir.22855</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chir.22855" target="_blank" >10.1002/chir.22855</a>

Result language
angličtina
Original language name
Enantioselective Complexation of 1‐Phenylethanol with Chiral Compounds Bearing Urea Moiety.
Original language description
A detailed study of diastereomeric complexes of chiral ureido-1,1′-binaphthalene derivatives with chiral 1-phenylethanol showed that a derivative bearing only one urea unit makes five times more stable complex with (S)-enantiomer than with (R)-enantiomer of the alcohol. This phenomenon could be used in chiral discrimination processes. The influence of individual parts of the structure on the complexation properties is shown. The probable structure of diastereomeric complexes based on experimental results and computational methods is proposed.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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