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Enantioselective Complexation of 1‐Phenylethanol with Chiral Compounds Bearing Urea Moiety.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F18%3A00490484" target="_blank" >RIV/61388963:_____/18:00490484 - isvavai.cz</a>

  • Alternative codes found

    RIV/67985858:_____/18:00490484 RIV/60461373:22310/18:43917053

  • Result on the web

    <a href="http://dx.doi.org/10.1002/chir.22855" target="_blank" >http://dx.doi.org/10.1002/chir.22855</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/chir.22855" target="_blank" >10.1002/chir.22855</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Enantioselective Complexation of 1‐Phenylethanol with Chiral Compounds Bearing Urea Moiety.

  • Original language description

    A detailed study of diastereomeric complexes of chiral ureido-1,1′-binaphthalene derivatives with chiral 1-phenylethanol showed that a derivative bearing only one urea unit makes five times more stable complex with (S)-enantiomer than with (R)-enantiomer of the alcohol. This phenomenon could be used in chiral discrimination processes. The influence of individual parts of the structure on the complexation properties is shown. The probable structure of diastereomeric complexes based on experimental results and computational methods is proposed.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10401 - Organic chemistry

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Chirality

  • ISSN

    0899-0042

  • e-ISSN

  • Volume of the periodical

    30

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

    798-806

  • UT code for WoS article

    000437270200010

  • EID of the result in the Scopus database

    2-s2.0-85044433610