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Evaluation of an ion source with a tubular nebulizer for microflow atmospheric pressure chemical ionization

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F18%3A00490859" target="_blank" >RIV/61388963:_____/18:00490859 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11310/18:10391624

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s00706-018-2172-4" target="_blank" >http://dx.doi.org/10.1007/s00706-018-2172-4</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s00706-018-2172-4" target="_blank" >10.1007/s00706-018-2172-4</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Evaluation of an ion source with a tubular nebulizer for microflow atmospheric pressure chemical ionization

  • Original language description

    An atmospheric pressure chemical ionization (APCI) source designed for microliter-per-minute flow rates (0.5-10.0 mm(3)/min) was constructed. A simple resistively heated 1/8 in. OD tube-based nebulizer, together with a corona-discharge electrode was positioned in front of the entrance capillary of a mass spectrometer. Working parameters of the ion source were optimized, and its performance was evaluated. The limit of detection for directly infused acridine was found to be lower for micro-APCI (10 fmol/s) than for conventional APCI (170 fmol/s), and the linear dynamic range was significantly wider for the micro-APCI source. The micro-APCI and conventional APCI sources provided similar, but not identical mass spectra. The micro-APCI source was used as a detector for high-performance liquid chromatography at 10 mm(3)/min, the limit of detection for acridine was 690 fmol, which was about ten times lower value than in conventional HPLC.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10406 - Analytical chemistry

Result continuities

  • Project

    <a href="/en/project/GA16-01639S" target="_blank" >GA16-01639S: Micro- and nanoflow atmospheric pressure ionizations for bioanalytical mass spectrometry</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Monatshefte fur Chemie

  • ISSN

    0026-9247

  • e-ISSN

  • Volume of the periodical

    149

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    AT - AUSTRIA

  • Number of pages

    8

  • Pages from-to

    987-994

  • UT code for WoS article

    000433333300001

  • EID of the result in the Scopus database

    2-s2.0-85042070102