First total synthesis of ent-asperparaline C and assignment of the absolute configuration of asperparaline C

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F19%3A00504309" target="_blank" >RIV/61388963:_____/19:00504309 - isvavai.cz</a>

Result on the web

<a href="https://pubs.rsc.org/en/content/articlelanding/2019/CC/C9CC00945K#!divAbstract" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2019/CC/C9CC00945K#!divAbstract</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/c9cc00945k" target="_blank" >10.1039/c9cc00945k</a>

Result language

angličtina

Original language name

First total synthesis of ent-asperparaline C and assignment of the absolute configuration of asperparaline C

Original language description

The first asymmetric total synthesis of a member of the asperparaline family was accomplished and the unknown absolute configuration of asperparaline C has been determined to be all-(S). The key steps of the synthesis are an oxidative radical cyclization, a selective reduction of one of the tertiary amides, a singlet oxygen Diels-Alder reaction and a reductive spirocyclization.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10401 - Organic chemistry

Project

—

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2019

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Chemical Communications

ISSN

1359-7345

e-ISSN

—

Volume of the periodical

55

Issue of the periodical within the volume

27

Country of publishing house

GB - UNITED KINGDOM

Number of pages

4

Pages from-to

3931-3934

UT code for WoS article

000463952600015

EID of the result in the Scopus database

2-s2.0-85063944586