Tandem Anionic oxy-Cope Rearrangement/Oxygenation Reactions as a Versatile Method for Approaching Diverse Scaffolds

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F20%3A00522955" target="_blank" >RIV/61388963:_____/20:00522955 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/20:10421841
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201916188" target="_blank" >https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201916188</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.201916188" target="_blank" >10.1002/anie.201916188</a>

Result language
angličtina
Original language name
Tandem Anionic oxy-Cope Rearrangement/Oxygenation Reactions as a Versatile Method for Approaching Diverse Scaffolds
Original language description
Tandem anionic oxy-Cope rearrangement/radical oxygenation reactions provide delta,epsilon-unsaturated alpha-(aminoxy) carbonyl compounds, which serve as convenient precursors to diverse compound classes. Functionalized carbocycles are accessible by very rare all-carbon 5-endo-trig cyclizations, but also common 5-exo-trig radical cyclizations, based on the persistent radical effect. The tandem reactions can be further extended by highly diastereoselective allylation or reduction steps to give complex scaffolds.
Czech name
—
Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry

Project
<a href="/en/project/GA16-18513S" target="_blank" >GA16-18513S: Tandem Sigmatropic Rearrangement/Radical Reactions - A New Productive Alliance in Organic Chemistry</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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