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Atomic-scale charge distribution mapping of single substitutional p- and n-type dopants in graphene

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F20%3A00539691" target="_blank" >RIV/61388963:_____/20:00539691 - isvavai.cz</a>

  • Alternative codes found

    RIV/68378271:_____/20:00539691 RIV/61989592:15310/20:73604270 RIV/00216208:11320/20:10423792

  • Result on the web

    <a href="https://doi.org/10.1021/acssuschemeng.9b07623" target="_blank" >https://doi.org/10.1021/acssuschemeng.9b07623</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/acssuschemeng.9b07623" target="_blank" >10.1021/acssuschemeng.9b07623</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Atomic-scale charge distribution mapping of single substitutional p- and n-type dopants in graphene

  • Original language description

    To improve the understanding of the role of p- and n-type dopants in graphene’s local chemical activity and quantification of its interaction with single molecules, we report an atomic-scale investigation of single boron (B) and nitrogen (N) dopants in graphene and their interactions with CO molecules by means of atomic force microscopy (AFM) and Kelvin probe force microscopy (KPFM) experiments and theoretical calculations. We infer that N/B doping significantly increases/lowers the chemical interaction of graphene with individual CO molecules as a result of weak electrostatic forces induced by distinct charge distribution around the dopant site. High-resolution AFM images allow dopant discrimination and their atomic-scale structural characterization, which may be crucial for the atomic-scale design of graphene derivatives with relevant potential applications in molecular sensing and catalysis.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10403 - Physical chemistry

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ACS Sustainable Chemistry & Engineering

  • ISSN

    2168-0485

  • e-ISSN

  • Volume of the periodical

    8

  • Issue of the periodical within the volume

    8

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    8

  • Pages from-to

    3437-3444

  • UT code for WoS article

    000518088700040

  • EID of the result in the Scopus database

    2-s2.0-85080064651