Oxidative nucleophilic alkoxylation of nitrobenzenes

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F21%3A00538873" target="_blank" >RIV/61388963:_____/21:00538873 - isvavai.cz</a>

Result on the web

<a href="https://doi.org/10.1039/D0QO01291B" target="_blank" >https://doi.org/10.1039/D0QO01291B</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/d0qo01291b" target="_blank" >10.1039/d0qo01291b</a>

Result language

angličtina

Original language name

Oxidative nucleophilic alkoxylation of nitrobenzenes

Original language description

Oxidative nucleophilic aromatic substitution of hydrogen in nitroaromatics with potassium alkoxides derived from primary, secondary or tertiary alcohols in the presence of oxygen was achieved. Mechanistic investigations suggest the formation of a deprotonated σH adduct. The products showed good reactivity in nucleophilic aromatic substitution of the nitro group with oxygen or nitrogen nucleophiles to access selectively substituted aromatic compounds.

Czech name

—

Czech description

—

Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10401 - Organic chemistry

Project

<a href="/en/project/GC18-00215J" target="_blank" >GC18-00215J: Novel synthetic approaches to organic sulfur pentafluorides</a><br>

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2021

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Organic Chemistry Frontiers

ISSN

2052-4129

e-ISSN

2052-4129

Volume of the periodical

8

Issue of the periodical within the volume

1

Country of publishing house

GB - UNITED KINGDOM

Number of pages

5

Pages from-to

77-81

UT code for WoS article

000605450500009

EID of the result in the Scopus database

2-s2.0-85099064199