Synthesis, crystallographic and spectroscopic characterization, and theoretical elucidation of an elusive aminyl radical containing a Cu<sup>II</sup>-aminyl-iminosemiquinone complex
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F21%3A00540721" target="_blank" >RIV/61388963:_____/21:00540721 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1039/D0CC07378D" target="_blank" >https://doi.org/10.1039/D0CC07378D</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d0cc07378d" target="_blank" >10.1039/d0cc07378d</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis, crystallographic and spectroscopic characterization, and theoretical elucidation of an elusive aminyl radical containing a Cu<sup>II</sup>-aminyl-iminosemiquinone complex
Original language description
An elusive aminyl radical and an iminosemiquinone radical-coordinated square pyramidal Cu(ii) complex (1) have been isolated by the reaction between the noninnocent ligand H4LPy(AP)and Cu(ClO4)2·6H2O in the presence of Et3N and air as the sole oxidant. The geometry and electronic structure of the complex were concluded by X-ray crystallography, magnetic and EPR measurements, and density functional theory (DFT) calculations. This work reports the first crystallographic example of the two different types of radicals co-existing in a stable complex.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemical Communications
ISSN
1359-7345
e-ISSN
1364-548X
Volume of the periodical
57
Issue of the periodical within the volume
11
Country of publishing house
GB - UNITED KINGDOM
Number of pages
4
Pages from-to
1352-1355
UT code for WoS article
000617030000014
EID of the result in the Scopus database
2-s2.0-85101098377