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Synthesis, crystallographic and spectroscopic characterization, and theoretical elucidation of an elusive aminyl radical containing a Cu<sup>II</sup>-aminyl-iminosemiquinone complex

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F21%3A00540721" target="_blank" >RIV/61388963:_____/21:00540721 - isvavai.cz</a>

  • Result on the web

    <a href="https://doi.org/10.1039/D0CC07378D" target="_blank" >https://doi.org/10.1039/D0CC07378D</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/d0cc07378d" target="_blank" >10.1039/d0cc07378d</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis, crystallographic and spectroscopic characterization, and theoretical elucidation of an elusive aminyl radical containing a Cu<sup>II</sup>-aminyl-iminosemiquinone complex

  • Original language description

    An elusive aminyl radical and an iminosemiquinone radical-coordinated square pyramidal Cu(ii) complex (1) have been isolated by the reaction between the noninnocent ligand H4LPy(AP)and Cu(ClO4)2·6H2O in the presence of Et3N and air as the sole oxidant. The geometry and electronic structure of the complex were concluded by X-ray crystallography, magnetic and EPR measurements, and density functional theory (DFT) calculations. This work reports the first crystallographic example of the two different types of radicals co-existing in a stable complex.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10403 - Physical chemistry

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Chemical Communications

  • ISSN

    1359-7345

  • e-ISSN

    1364-548X

  • Volume of the periodical

    57

  • Issue of the periodical within the volume

    11

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    4

  • Pages from-to

    1352-1355

  • UT code for WoS article

    000617030000014

  • EID of the result in the Scopus database

    2-s2.0-85101098377