Synthesis, crystallographic and spectroscopic characterization, and theoretical elucidation of an elusive aminyl radical containing a Cu-II-aminyl-iminosemiquinone complex

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15640%2F21%3A73607327" target="_blank" >RIV/61989592:15640/21:73607327 - isvavai.cz</a>
Result on the web
<a href="https://pubs.rsc.org/en/content/articlelanding/2021/CC/D0CC07378D" target="_blank" >https://pubs.rsc.org/en/content/articlelanding/2021/CC/D0CC07378D</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d0cc07378d" target="_blank" >10.1039/d0cc07378d</a>

Result language
angličtina
Original language name
Synthesis, crystallographic and spectroscopic characterization, and theoretical elucidation of an elusive aminyl radical containing a Cu-II-aminyl-iminosemiquinone complex
Original language description
An elusive aminyl radical and an iminosemiquinone radical-coordinated square pyramidal Cu(ii) complex (1) have been isolated by the reaction between the noninnocent ligand H4LPy(AP) and Cu(ClO4)(2)center dot 6H(2)O in the presence of Et3N and air as the sole oxidant. The geometry and electronic structure of the complex were concluded by X-ray crystallography, magnetic and EPR measurements, and density functional theory (DFT) calculations. This work reports the first crystallographic example of the two different types of radicals co-existing in a stable complex.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
21001 - Nano-materials (production and properties)

Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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